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Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 12.07.2014 Page 1 of 8 Phosphoric Acid,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Phosphoric Acid,ACS Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25470B Recommended uses of the product and uses restrictions on use: Manufacturer Details: AquaPhoenix Scientific 9 Barnhart Drive, Hanover, PA 17331 Supplier Details: Fisher Science Education 15 Jet View Drive, Rochester, NY 14624 Emergency telephone number: Fisher Science Education Emergency Telephone No.: 800-535-5053 SECTION 2 : Hazards identification Classification of the substance or mixture: Corrosive Skin corrosion, category 1B Corrosive to metals, category 1 Corrosive to Metals 1 Skin Corrosion 1B Signal word :Danger Hazard statements: May be corrosive to metals Causes severe skin burns and eye damage Precautionary statements: If medical advice is needed, have product container or label at hand Keep out of reach of children Read label before use Do not breathe dust/fume/gas/mist/vapours/spray Wash … thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Keep only in original container Do not eat, drink or smoke when using this product Immediately call a POISON CENTER or doctor/physician Specific treatment (see … on this label) Wash contaminated clothing before reuse IF SWALLOWED: Rinse mouth. Do NOT induce vomiting IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 12.07.2014 Page 2 of 8 Phosphoric Acid,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Store locked up Store in a corrosive resistant/… container with a resistant inner liner Dispose of contents/container to … Conc 10% to <25%: eye="" irritation="" 2,="" skin="" irritation="" 2="" conc=""><10%: not="" classified="" for="" physical="" or="" health="" hazards="" under="" ghs.="" other="" non-ghs="" classification:="" whmis="" e="" nfpa/hmis="" nfpa="" scale="" (0-4)="" hmis="" ratings="" (0-4)="" section="" 3="" :="" composition/information="" on="" ingredients="" ingredients:="" cas="" 7664-38-2="" phosphoric="" acid="">85 % CAS 7732-18-5 Deionized Water <15 %="" percentages="" are="" by="" weight="" section="" 4="" :="" first="" aid="" measures="" description="" of="" first="" aid="" measures="" after="" inhalation:="" seek="" medical="" attention="" immediately.="" move="" exposed="" individual="" to="" fresh="" air.="" loosen="" clothing="" as="" necessary="" and="" position="" individual="" in="" a="" comfortable="" position.="" after="" skin="" contact:="" remove="" contaminated="" clothing="" and="" wash="" before="" reuse="" or="" discard.="" rinse="" skin="" with="" for="" 30="" minutes="" with="" deluge="" of="" water="" or="" under="" a="" shower.="" seek="" immediate="" medical="" attention.wash="" affected="" area="" with="" soap="" and="" water.="" after="" eye="" contact:="" rinse="" immediately="" with="" plenty="" of="" water,="" also="" under="" the="" eyelids,="" for="" at="" least="" 30="" minutes.="" remove="" contact="" lens(es)="" if="" able="" to="" do="" so="" during="" rinsing.="" seek="" medical="" attention="" immediately.protect="" unexposed="" eye.="" after="" swallowing:="" seek="" medical="" attention="" immediately.="" rinse="" mouth="" thoroughly.="" do="" not="" induce="" vomiting.="" have="" exposed="" individual="" drink="" sips="" of="" water.="" safety="" data="" sheet="" according="" to="" 29cfr1910/1200="" and="" ghs="" rev.="" 3="" effective="" date="" :="" 12.07.2014="" page="" 3="" of="" 8="" phosphoric="" acid,acs="" created="" by="" global="" safety="" management,="" inc.="" -tel:="" 1-813-435-5161="" -="" www.gsmsds.com="" most="" important="" symptoms="" and="" effects,="" both="" acute="" and="" delayed:="" irritation,="" nausea,headache,="" shortness="" of="" breath.may="" cause="" severe="" burns="" and="" ulcerations.="" may="" cause="" severe="" burn="" and="" irreversible="" eye="" injury.="" may="" cause="" gastrointestinal="" tract="" burns,="" corrosion="" and="" permanent="" tissue="" damage="" of="" the="" digestive="" tract="" and="" esophagus;="" indication="" of="" any="" immediate="" medical="" attention="" and="" special="" treatment="" needed:="" if="" seeking="" medical="" attention,="" provide="" sds="" document="" to="" physician.wipe="" off="" contact="" areas="" with="" a="" dry="" cloth="" if="" possible,="" before="" flushing="" with="" water.="" dispose="" of="" cloth="" by="" soaking="" in="" water.="" neutralize="" the="" soaking="" solution="" with="" sodium="" hydroxide="" solution.="" section="" 5="" :="" firefighting="" measures="" extinguishing="" media="" suitable="" extinguishing="" agents:="" if="" in="" laboratory="" setting,="" follow="" laboratory="" fire="" suppression="" procedures.="" use="" appropriate="" fire="" suppression="" agents="" for="" adjacent="" combustible="" materials="" or="" sources="" of="" ignition="" for="" safety="" reasons="" unsuitable="" extinguishing="" agents:="" special="" hazards="" arising="" from="" the="" substance="" or="" mixture:="" hydrogen="" gas="" is="" released="" in="" contact="" with="" most="" metals.="" combustion="" products="" may="" include="" carbon="" oxides="" or="" other="" toxic="" vapors.combustion="" products="" may="" include="" phosphine,="" oxides="" of="" phosphorus,="" and="" hydrogen="" gas.="" advice="" for="" firefighters:="" protective="" equipment:="" wear="" protective="" equipment="" use="" respiratory="" protective="" device="" against="" the="" effects="" of="" fumes/dust/aerosol/vapor="" .="" use="" niosh-approved="" respiratory="" protection/breathing="" apparatus.="" additional="" information="" (precautions):="" move="" product="" containers="" away="" from="" fire="" or="" keep="" cool="" with="" water="" spray="" as="" a="" protective="" measure,="" where="" feasible.="" section="" 6="" :="" accidental="" release="" measures="" personal="" precautions,="" protective="" equipment="" and="" emergency="" procedures:="" wear="" protective="" equipment.="" avoid="" contact="" with="" eyes,="" skin,="" and="" clothing.="" use="" respiratory="" protective="" device="" against="" the="" effects="" of="" fumes/dust/aerosol.="" keep="" unprotected="" persons="" away.="" ensure="" adequate="" ventilation.keep="" away="" from="" ignition="" sources.="" protect="" from="" heat.stop="" the="" spill,="" if="" possible.="" contain="" spilled="" material="" by="" diking="" or="" using="" inert="" absorbent.="" transfer="" to="" a="" disposal="" or="" recovery="" container.="" environmental="" precautions:="" prevent="" from="" reaching="" drains,="" sewer="" or="" waterway.="" collect="" contaminated="" soil="" for="" characterization="" per="" section="" 13="" methods="" and="" material="" for="" containment="" and="" cleaning="" up:="" absorb="" spillage="" to="" prevent="" material="" damage="" due="" to="" corrosiveness="" to="" metal.="" if="" in="" a="" laboratory="" setting,="" follow="" chemical="" hygiene="" plan="" procedures.place="" into="" properly="" labeled="" containers="" for="" recovery="" or="" disposal.="" if="" necessary,="" use="" trained="" response="" staff/contractor.collect="" liquids="" using="" inert="" absorbent="" material.="" reference="" to="" other="" sections:="" section="" 7="" :="" handling="" and="" storage="" precautions="" for="" safe="" handling:="" wash="" hands="" after="" handling.="" do="" not="" mix="" with="" bases.="" use="" in="" a="" chemical="" fume="" hood.follow="" good="" hygiene="" procedures="" when="" handling="" chemical="" materials.="" do="" not="" eat,="" drink,="" smoke,="" or="" use="" personal="" products="" when="" handling="" chemical="" substances.="" if="" in="" a="" laboratory="" setting,="" follow="" chemical="" hygiene="" plan.use="" only="" in="" well="" ventilated="" areas.prevent="" contact="" with="" eyes,="" skin,="" and="" clothing="" conditions="" for="" safe="" storage,="" including="" any="" incompatibilities:="" store="" away="" from="" oxidizing="" agents.store="" in="" cool,="" dry="" conditions="" in="" well="" sealed="" containers.="" keep="" container="" tightly="" sealed.do="" not="" store="" under="" direct="" sun="" light.="" do="" not="" pile="" up="" the="" containers.="" do="" not="" store="" at="" temperatures="" close="" to="" freezing="" point.container="" materials="" should="" be="" made="" of="" stainless="" steel="" 316-l,="" high-density="" polyethylene,="" or="" safety="" data="" sheet="" according="" to="" 29cfr1910/1200="" and="" ghs="" rev.="" 3="" effective="" date="" :="" 12.07.2014="" page="" 4="" of="" 8="" phosphoric="" acid,acs="" created="" by="" global="" safety="" management,="" inc.="" -tel:="" 1-813-435-5161="" -="" www.gsmsds.com="" glass.provide="" ventilation="" for="" containers.="" avoid="" storage="" near="" extreme="" heat,="" ignition="" sources="" or="" open="" flame.="" store="" away="" from="" foodstuffs.="" section="" 8="" :="" exposure="" controls/personal="" protection="" control="" parameters:="" 7664-38-2,="" phosphoric="" acid,="" acgih="" tlv:="" 1="" mg/m³="" as="" twa="" 7664-38-2,="" phosphoric="" acid,="" acgih="" tlv="" 3="" mg/m³="" as="" stel="" 7664-38-2,="" phosphoric="" acid,="" osha="" pel†:="" twa="" 1="" mg/m3="" (see="" 29="" cfr="" 1910.1000="" appendix="" g)="" 7664-38-2,="" phosphoric="" acid,="" niosh="" rel:="" twa="" 1="" mg/m3="" 7664-38-2,="" phosphoric="" acid,="" niosh="" rel="" st:="" 3="" mg/m3="" 7664-38-2,="" phosphoric="" acid,="" niosh="" idlh:="" 1000="" mg/m3="" appropriate="" engineering="" controls:="" emergency="" eye="" wash="" fountains="" and="" safety="" showers="" should="" be="" available="" in="" the="" immediate="" vicinity="" of="" use/handling.provide="" exhaust="" ventilation="" or="" other="" engineering="" controls="" to="" keep="" the="" airborne="" concentrations="" of="" vapor="" or="" dusts="" (total/respirable)="" below="" the="" applicable="" workplace="" exposure="" limits="" (occupational="" exposure="" limits-oels)="" indicated="" above.="" respiratory="" protection:="" use="" suitable="" respiratory="" protective="" device="" when="" high="" concentrations="" are="" present.="" use="" suitable="" respiratory="" protective="" device="" when="" aerosol="" or="" mist="" is="" formed.="" for="" spills,="" respiratory="" protection="" may="" be="" advisable.="" protection="" of="" skin:="" the="" glove="" material="" has="" to="" be="" impermeable="" and="" resistant="" to="" the="" product/="" the="" substance/="" the="" preparation="" being="" used/handled.selection="" of="" the="" glove="" material="" on="" consideration="" of="" the="" penetration="" times,="" rates="" of="" diffusion="" and="" the="" degradation.="" eye="" protection:="" safety="" glasses="" with="" side="" shields="" or="" goggles.="" general="" hygienic="" measures:="" the="" usual="" precautionary="" measures="" are="" to="" be="" adhered="" to="" when="" handling="" chemicals.="" keep="" away="" from="" food,="" beverages="" and="" feed="" sources.="" immediately="" remove="" all="" soiled="" and="" contaminated="" clothing.="" wash="" hands="" before="" breaks="" and="" at="" the="" end="" of="" work.="" do="" not="" inhale="" gases/fumes/dust/mist/vapor/aerosols.="" avoid="" contact="" with="" the="" eyes="" and="" skin.="" section="" 9="" :="" physical="" and="" chemical="" properties="" appearance="" (physical="" state,color):="" clear,="" colorless="" liquid="" explosion="" limit="" lower:="" explosion="" limit="" upper:="" not="" determined="" not="" determined="" odor:="" odorless="" vapor="" pressure:="" not="" determined="" odor="" threshold:="" not="" determined="" vapor="" density:="" 3.4="" ph-value:="" not="" determined="" relative="" density:="" 1.680="" melting/freezing="" point:="" 21°c="" solubilities:="" soluble="" in="" water="" boiling="" point/boiling="" range:="" 158°c="" partition="" coefficient="" (n-="" octanol/water):="" not="" determined="" flash="" point="" (closed="" cup):="" not="" determined="" auto/self-ignition="" temperature:="" not="" determined="" safety="" data="" sheet="" according="" to="" 29cfr1910/1200="" and="" ghs="" rev.="" 3="" effective="" date="" :="" 12.07.2014="" page="" 5="" of="" 8="" phosphoric="" acid,acs="" created="" by="" global="" safety="" management,="" inc.="" -tel:="" 1-813-435-5161="" -="" www.gsmsds.com="" evaporation="" rate:="" not="" determined="" decompositiontemperature:="" 300°c="" flammability="" (solid,gaseous):="" not="" applicable="" viscosity:="" a.="" kinematic:not="" determined="" b.="" dynamic:="" not="" determined="" density:="" not="" determined="" additional="" property::hygroscopic.="" specific="" gravity:1.680="" molecular="" weight:="" :98.00="" g/mol="" section="" 10="" :="" stability="" and="" reactivity="" reactivity:="" chemical="" stability:this="" hygroscopic="" substance="" pulls="" moisture="" from="" air.="" no="" decomposition="" if="" used="" and="" stored="" according="" to="" specifications.="" possible="" hazardous="" reactions:="" conditions="" to="" avoid:metals.="" exposure="" to="" moist="" air="" or="" water.="" incompatible="" materials.="" excess="" heat.="" store="" away="" from="" oxidizing="" agents,="" strong="" acids="" or="" bases.="" incompatible="" materials:metals.="" bases="" .="" alcohols.="" amines.="" halogenated="" agents.="" organic="" peroxides.="" amides.="" azo.="" diazo.="" hydrazines.="" chlorates.="" carbamates.="" esters.="" fluorides.="" phenols.="" cresols="" .="" organophosphates.="" phosphothioates.="" epoxides.="" combustible="" and="" flammable="" materials.="" explosives.="" alkalines.="" nitromethane.="" sodium="" tetrahydroborate.="" mercaptans.="" aldehydes.="" ketones.="" glycols.="" cyanides.="" sulfides.="" caustics.="" strong="" acids.carbides.="" strong="" bases.fulminates.="" reducing="" agents.="" nitrates.="" acetic="" acid.="" oxidizing="" agents="" hazardous="" decomposition="" products:phosophine.="" oxides="" of="" phosphorus.="" hydrogen="" gas="" is="" released="" in="" contact="" with="" most="" metals.="" section="" 11="" :="" toxicological="" information="" acute="" toxicity:="" oral:="" 2600="" mg/kg="" bw="" ld50="" for="" a="" 10%="" solution="" of="" 75.4%="" thermalphosphoric="" acid="" (rat)="" oral:="" 1530="" mg/m3="" ld50="" oral-rat:="" (7764-38-2)="" inhalation:="">850mg/m3 LC50 inhalation-rat (1h) (7664-38-2) Chronic Toxicity: No additional information. Corrosion Irritation: Dermal: Section 2 Classified as a skin corrosion Ocular: Section 2 (eye damage is presumed withSkin 1 classification) Eye Damage Dermal: May cause severe burns and ulcerations. Ocular: May cause severe burn and irreversible eyedamage Sensitization: No additional information. Single Target Organ (STOT): No additional information. Numerical Measures: No additional information. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 3 Effective date : 12.07.2014 Page 6 of 8 Phosphoric Acid,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Carcinogenicity: IARC: Not listedNTP: Not listed Mutagenicity: No additional information. Reproductive Toxicity: No additional information. SECTION 12 : Ecological information Ecotoxicity Do not release to water: May release phosphates which will result in algae growth, increased turbidity, and depleted oxygen in the marine environment; at extremely high concentrations and/or quantities, this may be hazardous to fish or other marine organisms. LpH50 (median lethal pH) (96h) phosphoric acid (bluegill sunfish): 3-3.25 Adult brook trout survived 5 months exposure to pH levels of 5.0 and above. Total egg production was not affected