For the system described in exercises 4.15 and 4.16 we have the canonical partition function                                                               Show that...


For the system described in exercises 4.15 and 4.16 we have the canonical partition function






Show that





Use this result and the analogous formula for {NB} to show that {NA} / {NB} = qA/qB. Next consider the fluctuations from these mean values. Express the average of the square fluctua-tion, (NA}/ {NA} )2 , as appropriately weighted sums over states, and show that





Derive a similar expression for the fluctuations in NB.






May 13, 2022
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