One renewable energy fuel source is hydrogen. Hydrogen fuel cells use the chemical energy of hydrogen to cleanly and efficiently produce electricity. However, hydrogen is usually “tied-up” in other molecules such as hydrocarbons and must be harvested. The two main ways this is done is by (1) “splitting” water to make hydrogen gas or (2) reforming natural gas (methane). However, process 2 means we are using fossil fuels (non-renewable energy sources) to create renewable energy.
(1) H2O(l) → H2(g) + ½ O2(g) ΔHrxn = +285.8 kJ/mol
(2) CH4(g) + 2H2O(g) → CO2(g) + H2(g) ΔHrxn = _______ kJ/mol
Using the standard enthalpies of formation in the table below and equation 7.15 (Tro pg. 292), calculate ΔHrxnfor reaction 2. (I have a included an image of this equation)
Substance
ΔHf°(kJ/mol)
CH4(g)
-74.6
H2O(g)
-241.8
H2O(l)
-285.8
CO2(g)
-393.5
CO2(aq)
-413.8
b. compare the reaction enthalpies for splitting water and for reforming natural gas.
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