One renewable energy fuel source is hydrogen. Hydrogen fuel cells use the chemical energy of hydrogen to cleanly and efficiently produce electricity. However, hydrogen is usually “tied-up” in other...



One renewable energy fuel source is hydrogen. Hydrogen fuel cells use the chemical energy of hydrogen to cleanly and efficiently produce electricity. However, hydrogen is usually “tied-up” in other molecules such as hydrocarbons and must be harvested. The two main ways this is done is by (1) “splitting” water to make hydrogen gas or (2) reforming natural gas (methane). However, process 2 means we are using fossil fuels (non-renewable energy sources) to create renewable energy.


(1) H2O(l) → H2(g) + ½ O2(g)                      ΔHrxn = +285.8 kJ/mol


(2) CH4(g) + 2H2O(g) → CO2(g) + H2(g)    ΔHrxn = _______ kJ/mol


Using the standard enthalpies of formation in the table below and equation 7.15 (Tro pg. 292), calculate ΔHrxn
for reaction 2. (I have a included an image of this equation)






























Substance



ΔHf°(kJ/mol)



CH4(g)



-74.6



H2O(g)



-241.8



H2O(l)



-285.8



CO2(g)



-393.5



CO2(aq)



-413.8





b. compare the reaction enthalpies for splitting water and for reforming natural gas.



AH EAH] (products) - 4AH} (reactants)<br>SAH (products)<br>EMAHI (reactants)<br>ais equation, n, t<br>represents the stoichionmetric coefficients of<br>s the stoichiometric coefficients of the reactants, and AH; represek<br>es of formation. Keep in mind when using this equation that ele<br>states have AHị-0. Examples 7.11 and 7.12 demonstrate this proc<br>WATCH NOW!<br>

Extracted text: AH EAH] (products) - 4AH} (reactants) SAH (products) EMAHI (reactants) ais equation, n, t represents the stoichionmetric coefficients of s the stoichiometric coefficients of the reactants, and AH; represek es of formation. Keep in mind when using this equation that ele states have AHị-0. Examples 7.11 and 7.12 demonstrate this proc WATCH NOW!

Jun 11, 2022
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